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- W9617984 abstract "Rapid cooling of melts can produce amorphous structures in metallic materials which are normally crystalline. In many alloy systems metallic glasses exist over a wide compositional range which, in some cases, encompasses intermetallic compound compositions. In the Ti-Cu system, for example, glasses may be produced in the compositional range 30-70 atomic percent titanium; this range encompasses the intermetallic compounds TiCu and Ti2Cu which normally, of course, are crystalline. Absorption of hydrogen by crystalline TiCu and Ti2Cu and by the metallic glasses of corresponding compositions have been studied. Crystalline Ti2Cu and TiCu formed intermetallic compound hydrides, Ti2CUH<3 and TiCuH, respectively. Both hydrides were found to be unstable with respect to TiH2 +Cu and decomposed at temperatures above ∼200°. The corresponding metallic glasses, Ti0.65Cu0.35 (∼Ti2Cu) and TiCu, absorbed hydrogen without crystallization to form Ti0.65Cu0.35H1.1 and TiCuH0.89 (or TiCuH1.1). When the hydrogen containing glasses were moderately heated (150°–227°), amorphous TiH2 appeared to form. The data suggest that in the Ti-Cu-hydrogen system, the hydrogen absorption capacity is determined by the electronic structure; the crystal structure appears to be of less importance." @default.
- W9617984 created "2016-06-24" @default.
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- W9617984 date "1978-01-01" @default.
- W9617984 modified "2023-09-25" @default.
- W9617984 title "COMPARISON OF HYDROGEN ABSORPTION IN GLASSY AND CRYSTALLINE STRUCTURES" @default.
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- W9617984 doi "https://doi.org/10.1016/b978-0-08-022715-3.50040-0" @default.
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