Matches in SemOpenAlex for { <https://semopenalex.org/work/W963537531> ?p ?o ?g. }
- W963537531 endingPage "158" @default.
- W963537531 startingPage "152" @default.
- W963537531 abstract "In this work, two novel ruthenium-based compounds containing mercaptothiazolinate ligands were synthesized. A methanol (MeOH) solution containing [RuCl2(PPh3)3], 2-mercaptothiazoline (Hmctz) or 2-mercaptobenzothiazoline (Hmcbtz) (ligand/Ru = 2) and triethylamine (NEt3) was refluxed leading to the formation of neutral complexes with the general formula cis-[Ru(N–S)2(PPh3)2] (N–S = mctz− – complex 1; N–S = mcbtz− – complex 2). We used NMR (1H and 31P{1H}), vibrational spectroscopy (FTIR), and elemental analysis to analyze these two complexes. Cyclic voltammetry revealed that complexes 1 and 2 underwent a reversible one-electron process due to the Ru(III)/Ru(II) pair. Reactivity of the complexes 1 and 2 with dmso leading to the substitution of one PPh3 by dmso was observed (complexes 3 and 4). Complex 1 showed higher antimicrobial activity against Gram (+) and Gram (−) bacteria (Bacillus subtilis and Escherichia coli, respectively). The formation of complex [Ru(mctz)2(dmso)(PPh3)] (3) was faster than complex [Ru(mcbtz)2(dmso)(PPh3)] (4) and this may account for the higher antibacterial activity of complex 1. Single-crystal X-ray diffraction furnished the molecular structures of complex 1 and of the product of its reaction with dmso, [Ru(mctz)2(dmso)(PPh3)] (3)." @default.
- W963537531 created "2016-06-24" @default.
- W963537531 creator A5006472972 @default.
- W963537531 creator A5042543854 @default.
- W963537531 creator A5048764228 @default.
- W963537531 creator A5054608798 @default.
- W963537531 creator A5065597224 @default.
- W963537531 creator A5072102930 @default.
- W963537531 creator A5073232970 @default.
- W963537531 creator A5081462414 @default.
- W963537531 creator A5089652784 @default.
- W963537531 date "2015-09-01" @default.
- W963537531 modified "2023-10-17" @default.
- W963537531 title "Ruthenium (II) complexes containing 2-mercaptothiazolinates as ligands and evaluation of their antimicrobial activity" @default.
- W963537531 cites W1965060621 @default.
- W963537531 cites W1968846766 @default.
- W963537531 cites W1977398643 @default.
- W963537531 cites W1986187780 @default.
- W963537531 cites W1987828424 @default.
- W963537531 cites W1991641868 @default.
- W963537531 cites W1991643228 @default.
- W963537531 cites W1991767477 @default.
- W963537531 cites W1999031450 @default.
- W963537531 cites W2003683391 @default.
- W963537531 cites W2007290228 @default.
- W963537531 cites W2011726809 @default.
- W963537531 cites W2014281553 @default.
- W963537531 cites W2015555166 @default.
- W963537531 cites W2016947475 @default.
- W963537531 cites W2018547243 @default.
- W963537531 cites W2019200446 @default.
- W963537531 cites W2022548414 @default.
- W963537531 cites W2023613242 @default.
- W963537531 cites W2024153870 @default.
- W963537531 cites W2025005746 @default.
- W963537531 cites W2026526002 @default.
- W963537531 cites W2034335352 @default.
- W963537531 cites W2034599958 @default.
- W963537531 cites W2035825571 @default.
- W963537531 cites W2037973159 @default.
- W963537531 cites W2037994512 @default.
- W963537531 cites W2041063489 @default.
- W963537531 cites W2041267392 @default.
- W963537531 cites W2047481862 @default.
- W963537531 cites W2055783500 @default.
- W963537531 cites W2064095443 @default.
- W963537531 cites W2067894911 @default.
- W963537531 cites W2067979980 @default.
- W963537531 cites W2071725604 @default.
- W963537531 cites W2072510851 @default.
- W963537531 cites W2072551218 @default.
- W963537531 cites W2074035155 @default.
- W963537531 cites W2081865893 @default.
- W963537531 cites W2082257235 @default.
- W963537531 cites W2085826032 @default.
- W963537531 cites W2086882548 @default.
- W963537531 cites W2105189720 @default.
- W963537531 cites W2109511270 @default.
- W963537531 cites W2125810083 @default.
- W963537531 cites W2126996122 @default.
- W963537531 cites W2131350133 @default.
- W963537531 cites W2131502598 @default.
- W963537531 cites W2136020079 @default.
- W963537531 cites W2140821697 @default.
- W963537531 cites W2142773337 @default.
- W963537531 cites W2146260549 @default.
- W963537531 cites W2154790552 @default.
- W963537531 cites W2159733863 @default.
- W963537531 cites W2166923119 @default.
- W963537531 cites W2167132522 @default.
- W963537531 cites W2525039604 @default.
- W963537531 cites W285097125 @default.
- W963537531 cites W2950819230 @default.
- W963537531 cites W4211092410 @default.
- W963537531 cites W55268491 @default.
- W963537531 cites W2051316304 @default.
- W963537531 doi "https://doi.org/10.1016/j.ica.2015.07.022" @default.
- W963537531 hasPublicationYear "2015" @default.
- W963537531 type Work @default.
- W963537531 sameAs 963537531 @default.
- W963537531 citedByCount "15" @default.
- W963537531 countsByYear W9635375312016 @default.
- W963537531 countsByYear W9635375312017 @default.
- W963537531 countsByYear W9635375312018 @default.
- W963537531 countsByYear W9635375312021 @default.
- W963537531 countsByYear W9635375312022 @default.
- W963537531 countsByYear W9635375312023 @default.
- W963537531 crossrefType "journal-article" @default.
- W963537531 hasAuthorship W963537531A5006472972 @default.
- W963537531 hasAuthorship W963537531A5042543854 @default.
- W963537531 hasAuthorship W963537531A5048764228 @default.
- W963537531 hasAuthorship W963537531A5054608798 @default.
- W963537531 hasAuthorship W963537531A5065597224 @default.
- W963537531 hasAuthorship W963537531A5072102930 @default.
- W963537531 hasAuthorship W963537531A5073232970 @default.
- W963537531 hasAuthorship W963537531A5081462414 @default.
- W963537531 hasAuthorship W963537531A5089652784 @default.
- W963537531 hasConcept C115624301 @default.