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- W965404841 abstract "Two new lead (II) complexes, {(Pb(4-abs)(4,4 � -bipy)2 (H2O)3)·(4-abs)}n (1) and (Pb(4-abs)2(phen)2 (H2O)) (2), have been synthesized and characterized by elemental analyses, FTIR, thermal analyses, fluorescent spectra, and single-crystal X-ray analyses, where 4-abs is 4-aminobenzenesulfonate anion, 4,4 � -bipy is 4,4 � -bipyridine, phen is 1,10-phenanthroline. In these two complexes 4-abs shows three different modes, in complex 1 4-abs plays two roles: One serves as a bridging ligand, another is deprotonated and does not coordinate to the Pb atom, in complex 2 the 4-abs is a monodentate ligand. The structure of complex 1 is a one-dimensional polymer, whereas complex 2 is monomeric species. Intermolecular π-π interactions and hydrogen bonds are observed in these two complexes, which stabilize the crystal packing and give rise to supramolecular architectures." @default.
- W965404841 created "2016-06-24" @default.
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- W965404841 date "2014-01-01" @default.
- W965404841 modified "2023-09-23" @default.
- W965404841 title "Syntheses, structures, and characterizations of two new lead (II) supramolecular complexes containing 4-aminobenzenesulfonate ligand" @default.
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- W965404841 doi "https://doi.org/10.3233/mgc-140142" @default.
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