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- W965538956 abstract "Publisher Summary Transition metal carbonyls and their derivatives are remarkably effective and varied in their ability to catalyze reactions between unsaturated molecules. The carbonyl derivatives of cobalt are particularly active catalysts for such reactions and have been put to use in the industrial synthesis of higher aliphatic alcohols. The most important reason being that dicobalt octacarbonyl is a reasonably stable, commercially available, fairly well characterized compound which easily gives active catalytic intermediates. Most of the growth in our understanding of reactions catalyzed by dicobalt octacarbonyl has resulted from a study of the individual reactions of catalytic intermediates such as cobalt hydrocarbonyl. At much lower temperatures and pressures than are used in the corresponding catalytic processes, cobalt hydrocarbonyl has been found to give rise to similar reactions, but stoichiometrically. The carbon monoxide inhibition is most easily explained if the isomerization proceeds via the tricarbonyls rather than tetracarbonyls. An equally probable hypothesis is that under Oxo conditions the combination of temperature and carbon monoxide pressure result in the branched acylcobalt tricarbonyl for the first two olefins but a linear acylcobalt tetracarbonyl for ethyl acrylate." @default.
- W965538956 created "2016-06-24" @default.
- W965538956 creator A5025418127 @default.
- W965538956 creator A5079802673 @default.
- W965538956 date "1968-01-01" @default.
- W965538956 modified "2023-10-16" @default.
- W965538956 title "Catalysis by Cobalt Carbonyls" @default.
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- W965538956 cites W1685305523 @default.
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- W965538956 cites W1963665588 @default.
- W965538956 cites W1965808687 @default.
- W965538956 cites W1966399307 @default.
- W965538956 cites W1970246153 @default.
- W965538956 cites W1975317879 @default.
- W965538956 cites W1980824822 @default.
- W965538956 cites W1983266219 @default.
- W965538956 cites W1985507066 @default.
- W965538956 cites W1994943218 @default.
- W965538956 cites W1999626186 @default.
- W965538956 cites W2000836617 @default.
- W965538956 cites W2002718761 @default.
- W965538956 cites W2002925381 @default.
- W965538956 cites W2006761784 @default.
- W965538956 cites W2008465213 @default.
- W965538956 cites W2009130727 @default.
- W965538956 cites W2015889377 @default.
- W965538956 cites W2023642095 @default.
- W965538956 cites W2023720448 @default.
- W965538956 cites W2029342736 @default.
- W965538956 cites W2036831633 @default.
- W965538956 cites W2037950295 @default.
- W965538956 cites W2041440104 @default.
- W965538956 cites W2046487713 @default.
- W965538956 cites W2048402069 @default.
- W965538956 cites W2049228807 @default.
- W965538956 cites W2057635260 @default.
- W965538956 cites W2058903636 @default.
- W965538956 cites W2059070896 @default.
- W965538956 cites W2066072364 @default.
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- W965538956 cites W2077248217 @default.
- W965538956 cites W2081362618 @default.
- W965538956 cites W2082911089 @default.
- W965538956 cites W2084301298 @default.
- W965538956 cites W2086994860 @default.
- W965538956 cites W2104055018 @default.
- W965538956 cites W2132419292 @default.
- W965538956 cites W2138553189 @default.
- W965538956 cites W2169286538 @default.
- W965538956 cites W2313360591 @default.
- W965538956 cites W2315581375 @default.
- W965538956 cites W2315819250 @default.
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- W965538956 cites W2317823362 @default.
- W965538956 cites W2317829770 @default.
- W965538956 cites W2319250320 @default.
- W965538956 cites W2320136113 @default.
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- W965538956 cites W2321059440 @default.
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- W965538956 cites W2322515671 @default.
- W965538956 cites W2322877778 @default.
- W965538956 cites W2323643702 @default.
- W965538956 cites W2323975842 @default.
- W965538956 cites W2324357793 @default.
- W965538956 cites W2328756317 @default.
- W965538956 cites W2329262660 @default.
- W965538956 cites W2331043558 @default.
- W965538956 cites W2331071848 @default.
- W965538956 cites W2331287151 @default.
- W965538956 cites W2331357339 @default.
- W965538956 cites W2332127566 @default.
- W965538956 cites W2332710759 @default.
- W965538956 cites W2335070917 @default.
- W965538956 cites W2335105335 @default.
- W965538956 cites W2476225815 @default.
- W965538956 cites W3004895999 @default.
- W965538956 cites W3011347587 @default.
- W965538956 cites W402842071 @default.
- W965538956 cites W4206578905 @default.
- W965538956 cites W4235483902 @default.
- W965538956 cites W4244694814 @default.
- W965538956 cites W4248238486 @default.
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- W965538956 doi "https://doi.org/10.1016/s0065-3055(08)60588-2" @default.
- W965538956 hasPublicationYear "1968" @default.
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