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- W96555435 abstract "A complete solid-solution range exists in the system {YCa2}[Zr2](Fe3)O12{Y3}[Fe2](Fe3)O12. The Zr4+ ion is even larger than the Sn4+ ion and in this system apparently prefers only the octahedral sites. The behavior of the plot of nB(∞,0) vs. composition is similar to that of the Ca3Fe2Sn3O12Y3Fe2Fe3O12 system and corroborates the interaction model for garnets recently derived by gilleo. A small spontaneous magnetization is observed in the garnets {YCa2}[Zr2](Fe3)O12 and {YCa2}[Zr2](Me0.5Fe2.5)O12, Me = Al and Ga, indicating the es of magnetic sublattices among the tetrahedral sites. The garnet {YCa2}[Hf2](Fe3)O12 is readily formed. The Hf4+ ion, which is very nearly the same size as that of Zr4+, also prefers the octahedral site." @default.
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- W96555435 date "1960-05-01" @default.
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- W96555435 title "Crystal chemical and magnetic studies of garnet systems" @default.
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