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- W96563269 abstract "The mechanism of the tert-butylhydroperoxide-mediated, Pd(Quinox)-catalyzed Wacker-type oxidation was investigated to evaluate the hypothesis that a selective catalyst-controlled oxidation could be achieved by rendering the palladium coordinatively saturated using a bidentate amine ligand. The unique role of the Quinox ligand framework was probed via systematic ligand modifications. The modified ligands were evaluated through quantitative Hammett analysis, which supports a push-pull relationship between the electronically asymmetric quinoline and oxazoline ligand modules." @default.
- W96563269 created "2016-06-24" @default.
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- W96563269 date "2011-05-09" @default.
- W96563269 modified "2023-10-03" @default.
- W96563269 title "On the Mechanism of the Palladium-Catalyzed <i>tert</i>-Butylhydroperoxide-Mediated Wacker-Type Oxidation of Alkenes Using Quinoline-2-Oxazoline Ligands" @default.
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- W96563269 doi "https://doi.org/10.1021/ja2017043" @default.
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