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• W965683916 abstract "Abstract The X-ray single-crystal structures of N-trimetylsilyl acetamide CH3CONHSiMe3 (1), N-trimethylsilyl trifluoroacetamide CF3CONHSiMe3 (2) and N-trimethylsilyl benzamide PhCONHSiMe3 (3) have been determined. Quantum chemical calculations (B3LYP/6-311+G**, NBO analysis) were performed for gas phase optimized structures, proton affinities and N–H bond dissociation energies of amides 1–3 and their isostructural carbon analogs 4–6. The effect of silicon atom on structural features and intermolecular electron interactions was determined. Types of self-associates which can be formed by amides 1–3 in CCl4 solution were studies by infrared spectroscopy." @default.
• W965683916 created "2016-06-24" @default.
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• W965683916 date "2015-10-01" @default.
• W965683916 modified "2023-10-17" @default.
• W965683916 title "N-trimetylsilyl carboxamides RC(O)NHSiMe3 (R = Me, CF3, Ph): X-ray, DFT and FTIR study" @default.
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• W965683916 doi "https://doi.org/10.1016/j.molstruc.2015.06.018" @default.
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