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- W96618925 abstract "The compound YBa/sub 2/Cu/sub 3/O/sub x/ was given various oxidation treatments over a range of oxygen pressures from 0.02 to 200 MPa and temperatures up to 1223K. A tetragonal to orthorhombic transition was observed. At higher oxygen content, the orthorhombic phase becomes superconducting below 93K. At lower oxygen content, the tetragonal phase was stable down to room temperature. Doping by alkaline cations favored the formation of the orthorhombic phase even in a less oxidizing atmosphere, simultaneously improving the sinterability. The orthorhombic unit cell parameters, i.e. volume, bond lengths, and axial distortions, were found to correlate with the superconducting transition temperatures. These correlations are rationalized in terms of the interrelationship of oxygen stoichiometry with the lattice parameters of the orthorhombic phase. 15 refs., 11 figs., 1 tab." @default.
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- W96618925 date "1987-01-01" @default.
- W96618925 modified "2023-09-27" @default.
- W96618925 title "Superconductivity and the tailoring of lattice parameters of the compound YBa/sub 2/Cu/sub 3/O/sub x/" @default.
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