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- W966229144 abstract "运用电化学循环伏安(CV)和电化学原位石英晶体微天平(EQCM)研究了Pt电极表面不可逆吸附Sb原子的电化学特性以及Pt电极上Sb吸附原子对0.1 mol·L-1H2SO4溶液中1,2-丙二醇电催化氧化性能的影响.研究发现,当扫描电位的上限Eu≤0.50 V(SCE)时,Sb可以稳定地吸附在Pt电极表面,饱和覆盖度为0.34;通过控制电位扫描上限和扫描圈数剥离部份Sb可方便地得到Sbad的不同覆盖度;Pt电极表面Sb吸附原子能在较低的电位下吸附氧,可显著提高1,2-丙二醇电催化氧化活性.与Pt电极相比较,Sb饱和吸附原子修饰的Pt电极使1,2-丙二醇氧化的峰电流增加了近2倍.作者还从表面质量变化提供了吸附原子电催化作用的新数据." @default.
- W966229144 created "2016-06-24" @default.
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- W966229144 date "2003-01-01" @default.
- W966229144 modified "2023-10-17" @default.
- W966229144 title "铂电极上锑吸附原子对1，2-丙二醇电催化氧化性能的影响" @default.
- W966229144 hasPublicationYear "2003" @default.
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