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- W966451102 abstract "This chapter studies the subject of single-crystal X-ray diffraction under high pressure carried out to obtain crystallographic information on a high-pressure phase of AgGaS 2 above 4.2 GPa employing a diamond-anvil cell. The high-pressure phase has monoclinic symmetry with space group Cc, a = 8.065(4) A , b = 8.039(1)/ A, c = 6.226(3)/ A and s = 128.50(3)o at 5.6 GPa. The monoclinic cell can be approximated as a pseudotetragonal cell of a pt = b pt = 5.694(2) A, Cpt = 9.750(6)/ A, a pt = s pt = 88.70(3) o and Y pt = 89.82(3)o on the basis of the conventional chalcopyrite-type tetragonal cell. The principal response of the crystal structure to compression is a volume reduction of S 6 octahedral interstices. AgS 4 tetrahedra are more distorted than GaS 4 tetrahedra in the high-pressure phase." @default.
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- W966451102 date "1998-01-01" @default.
- W966451102 modified "2023-09-24" @default.
- W966451102 title "Distorted chalcopyrite-type structure of AgGaS2 under high pressure" @default.
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- W966451102 doi "https://doi.org/10.1016/b978-044482793-7/50061-8" @default.
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