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- W966781566 abstract "A novel one-dimensional chain complex [Pr2(bnbo)6(DMSO)4] (bnbo=3,5-binitro benzoyloxy, DMSO= dimethyl sulfoxide) with bridging carboxyl groups was synthesized and its structure has been determined by single-crystal X-ray methods. In the complex, a pair of adjacent metal ions are alternately connected by four or two carboxylate groups to form an infinite chain of 8-coordinated Pr3+ ions. The complex (Pr2C50H42N12O40S4 ) crystal system is triclinic, with space group P, a=14.2890(3), b=14.3427(3), c=20.1601(2)?; α=76.636(1), (=84.496(1), γ=60.316(1)°, V=3491.4(1)?3, Z=2, Mr =1861.02, Dc=1.770 g/cm3, (=1.608mm－1, F(000)=1856, the final R=0.0776 and wR=0.1724 for 8804 reflections with I > 2((I)." @default.
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- W966781566 date "2001-01-01" @default.
- W966781566 modified "2023-09-24" @default.
- W966781566 title "Synthesis and Crystal structure of [（Praseodymium）2（3,5—Binitro benzoyloxy）6（Dimethyl Sulfoxide）4]Complex" @default.
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