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- W968337966 abstract "Publisher Summary Sialyl Lewis X (sLe x ) ganglioside was first isolated from human kidney and found to be widespread as a tumor-associated ganglioside antigen. This chapter describes an efficient method for the synthesis of sLe x ganglioside and a position isomer, sialyl α (2→6)-Le x ganglioside. To investigate the role of sialic acid and L-fucose moieties for the functions of sLe x , syntheses of the chemically modified sialic acid- and L-fucose-containing sLe x ganglioside analogs are also described. These gangliosides and analogs could be used as effective probes for elucidation of cell–cell adhesion mechanisms. The chapter describes the synthesis of the 2-, 3-, and 4-deoxyfucose- containing sLe x oligosaccharides and their ceramide analogs, to clarify the structural features of the fucose moiety for the recognition of selectins, and the stereo-controlled synthesis of sLe x ganglioside analogs containing C 7 -Neu5Ac, C 8 -Neu5Ac, and 8-epi-Neu5Ac, clarifying the structural requirements of the sialic acid moiety for selectin recognition." @default.
- W968337966 created "2016-06-24" @default.
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- W968337966 date "1994-01-01" @default.
- W968337966 modified "2023-10-16" @default.
- W968337966 title "[15] Synthesis of Sialyl Lewis X ganglioside and analogs" @default.
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- W968337966 doi "https://doi.org/10.1016/0076-6879(94)42017-3" @default.
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