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- W968415212 abstract "This chapter discusses the principles of kinetics to clay minerals and soils and reviews present literature dealing with the kinetics of elemental reactions in these systems. Chemical kinetics deal with chemical reaction rates and these rates are explained in the chapter in terms of reaction mechanisms. There are two salient reasons for studying the rates of chemical reactions: first to predict how quickly a reaction mixture moves to its equilibrium state, and to reveal reaction mechanisms. One should realize that the rate law is determined by experimentation and it cannot be inferred by simply examining the overall chemical reaction equation. A number of equations have been employed to describe the kinetics of reactions in clay minerals and soils. These have included the first-order, Elovich, parabolic diffusion, zero–order, second–order, and two–constant rate equations. Data based on the kinetics of ion exchange in pure clay systems is used by soil chemists for many years to model kinetic reactions in heterogeneous soil systems. Vermiculite, montmorillonite, kaolinite, and hydrous mica vary drastically in their preferences, in ion binding affinities, and in types of ion exchange reactions. Soil systems are typically composed of complex mixtures of clay minerals, noncrystalline components, oxides, hydroxides, and organic matter. The inevitable interaction of these various components creates a heterogeneous exchange complex that makes the kinetics of ionic exchange in these systems difficult to study." @default.
- W968415212 created "2016-06-24" @default.
- W968415212 creator A5037434079 @default.
- W968415212 date "1986-01-01" @default.
- W968415212 modified "2023-10-16" @default.
- W968415212 title "Kinetics of Ionic Reactions in Clay Minerals and Soils" @default.
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- W968415212 doi "https://doi.org/10.1016/s0065-2113(08)60677-x" @default.
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