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- W968792145 abstract "The synthesis of a novel birnessite structure manganese oxide, Cs0.24MnO2, via a modified sol-gel route is reported in this work. The product was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and magnetic susceptibility. It is found that Cs0.24MnO2 crystallizes in a monoclinic phase with a nanosheet morphology. With lowering the temperature, Cs0.24MnO2 shows an antiferromagnetic transition at about 43.8 K, which is different from its paramagnetic K-counterpart. The effective moment of Mn ions in Cs0.24MnO2 is determined to be 4.2 μB, indicating a mixed valence of Mn4+/Mn3+." @default.
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- W968792145 date "2008-01-01" @default.
- W968792145 modified "2023-09-26" @default.
- W968792145 title "Synthesis and magnetic properties of a novel birnessite oxide Cs0.24MnO2" @default.
- W968792145 hasPublicationYear "2008" @default.
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