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• W968940391 endingPage "556" @default.
• W968940391 startingPage "465" @default.
• W968940391 abstract "Publisher Summary In the last few years, there has been the discovery and characterization of a number of complexes of aluminium and of gallium, by nuclear magnetic resonance (NMR). The solvation complexes are reported with water, dimethylformamide, N-methyl acetamide, ammonia, dimethyl sulphoxide, acetonitrile, and some mixed complexes containing either one of these components or acetone or tetrahydrofuran together with water. The solvation number for water on aluminium ion AP3⊕ is established as integrally six. Replacement of solvation water occurs by sulphate ion, phosphoric acid and dihydrogen phosphate ions, and by fluoride ion. The chapter describes the trisubstituted aluminium and gallium compounds, that have a general formula [MXYZ]n, where M is the metal and the substituents XYZ may be alkyl alkoxy, halide, siloxy, germyloxy, or various nitrogen bonded groups. Adducts of the substituted alanes and gallanes have some similarities to the dimers, as the dimers may be regarded as self adducts with a donor and acceptor centre in each half molecule. The metal chemical shifts are reported with respect to the ions M(H2O)3⊕6 whose shifts appear to be virtually independent of concentration. The formation of adducts produces a low-field shift that appears to depend upon the nature of the donor atom rather than upon the strength of the complex. The line widths of these molecules are very much broader than the tetrahedral species found to higher field." @default.
• W968940391 created "2016-06-24" @default.
• W968940391 creator A5026608761 @default.
• W968940391 date "1972-01-01" @default.
• W968940391 modified "2023-10-18" @default.
• W968940391 title "Nuclear Magnetic Resonance Spectroscopy in Liquids containing Compounds of Aluminium and Gallium" @default.
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