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- W969602502 abstract "The electronic properties of passive films formed on G3 and G30 alloys in bicarbonate/carbonate buffer solution were comparatively studied by electrochemical impedance spectra(EIS) and Mott-Schottky analysis, the chemical composition of the passive film formed on G3 alloy was detected by X-ray photoelectron spectroscopy (XPS). The results show that passive film on G3 alloy had better protection than that on G30 alloy. The transfer re- sistance, film resistance and diffusion resistance of the passive films on both alloys increased with increasing forma- tion potential, prolonging formation time, increasing pH value, decreasing formation temperature, and decreasing chloride and sulphide ions concentration. Mott-Schottky plot reveals that the passive films on the two alloys show a p-n semi-conductive character. XPS analysis indicates that the passive film on G3 alloy was composed of an inner Cr oxide and an outer Fe, Mo/Ni oxides. Keywords Nickel-based alloy; Electronic property; Passive film Article ID 1005-9040(2011)-02-304-09 45.45 20 19.5 0.52 8.18 3 1.13 1.7 0.5 0.45 G30 0.03 49 23 15 1 5.5 1.7 1.5 2 1 0.27" @default.
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- W969602502 date "2011-01-01" @default.
- W969602502 modified "2023-09-23" @default.
- W969602502 title "Electronic Properties of Passive Films Formed on G3 and G30 Nickel-based Alloys in Bicarbonate/Carbonate Buffer Solution" @default.
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