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- W970077219 abstract "Polybutadiene coated titania stationary phase (PBD-TiO 2 ) for HPLC has been prepared by immobilisation of polybutadiene on porous spherical microparticles of titania. Chromatographic retention of PBD-TiO 2 has been investigated using quantitative structure-retention relationships (QSRR). The logarithmic capacity factors (log k' ( P B D - T i O 2 ) ) were measured on PBD-TiO 2 in the methanol-water mobile phase (80:20, v/v) and compared with the nine structure descriptors of solutes. These studies were performed using the principal component analysis, cluster analysis, multiple linear regression and stepwise multiple regression. The results were compared with those obtained on the octadecyl silica stationary phase (ODS). The results obtained for PBD-TiO 2 occurred to be very close to those for ODS. Hydrophobic interactions dominated in the retention of solutes. The retention of aromatic compounds on PBD-TiO 2 stationary phase one can reasonably predict employing the empirical formula: log k' ( P B D - T i O 2 ) = 0.538 logP-1.099." @default.
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- W970077219 date "2004-01-01" @default.
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- W970077219 title "Chromatographic retention of polybutadiene coated titania stationary phase using quantitative structure-retention relationships" @default.
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