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- W970581247 abstract "The partial hydrolysis of titanium tetraisopropoxide in the presence of acetylacetone yields the complex [Ti4(μ3-O)2(μ2-OiPr)2(OiPr)8(acac)2] in which [(acac)(OiPr)2TiO(OiPr)Ti(OiPr)2] units are linked into dimers via the bridging oxide ion to form a ladder-like Ti4(μ3-O)2(μ2-OiPr)2 core containing five- and six-coordinate titanium and three-coordinate oxide ions that link the two units together through bonds to the five-coordinate titanium atoms. The Raman spectrum shows bands at 521 and 712 cm-1 that are assigned to ν(Ti−O) modes of bridging isopropoxide ligands and the μ3-oxygen, respectively." @default.
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- W970581247 date "1998-02-24" @default.
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- W970581247 title "X-ray Structure and Raman Spectrum of [Ti<sub>4</sub>(μ<sub>3</sub>-O)<sub>2</sub>(μ<sub>2</sub>-O<i><sup>i</sup></i>Pr)<sub>2</sub>(O<i><sup>i</sup></i>Pr)<sub>8</sub>(acac)<sub>2</sub>]: Presence of a Ti<sub>4</sub>(μ<sub>3</sub>-O)<sub>2</sub>(μ<sub>2</sub>-O<i><sup>i</sup></i>Pr)<sub>2</sub> Ladder-like Core" @default.
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- W970581247 doi "https://doi.org/10.1021/ic970942d" @default.
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