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- W97074654 abstract "Reaction mechanisms involved in the oxidation and reduction of hemoproteins by ultraviolet irradiation are discussed. The chemtcal processes leading to both anaerobic and aerobic ultraviolet reactions are considered. Data are included from a series of studies of ultraviolet effects on myoglobin, hemoglobin, cytochrome c, and hemoproteins. The conversion of trivalent Fe to divalent Fe in hemoproteins exposed to ultraviolet light was demonstrated. It was concluded that the primary reaction in ultravtolet-reduction of hemoproteins is restricted to the protein part, and in all probability to one or more of the aromatic amino acid rcsidues. This primary reaction does not produce any irreversible change in the protein. The primary reaction in ultraviolet- oxidation of hemoproteins is also probably restricted to the aromatic amino acids of the protein part. The participation of water in the reaction with the formation of OH-radicals is probably a condition for a reversible change in the protein. (C.H.)" @default.
- W97074654 created "2016-06-24" @default.
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- W97074654 date "1960-01-01" @default.
- W97074654 modified "2023-09-26" @default.
- W97074654 title "OXIDATION AND REDUCTION OF HEMOPROTEINS BY ULTRAVIOLET IRRADIATION" @default.
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