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- W970971805 abstract "Publisher Summary This chapter examines the effects of the introduced electric charges on the swelling behavior of a thermosensitive gel, N-isopropylacrylamide (NIPA), with the copolymer gels with sodium acrylate (NaA) or sodium styrene sulfonate (NaSS). It also includes the study of volume change behavior of NIPA gels from the discontinuous type (the volume phase transition) to the continuous one by a very small amount, less than 0.01 mole fractions. . This chapter also describes how polymer gels change their volume according to various perturbations in external conditions; temperature, solvent composition or pH. Following this, it includesthe solution nature of the shrunken state of NIPA gels. This explains the volume phase transition of gels. The increase in the discontinuity with ionization is explained by the increased Donnan osmotic pressure due to counter ions on the basis of the Flory-Huggins theory combined with the ideal Donnan osmotic pressure." @default.
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- W970971805 date "2000-01-01" @default.
- W970971805 modified "2023-09-27" @default.
- W970971805 title "Effect of electric charges on the volume phase transition of thermosensitive gels" @default.
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- W970971805 doi "https://doi.org/10.1016/b978-044450178-3/50003-2" @default.
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