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- W972484264 abstract "To harness the electroactivity of anthraquinone as an electrode material, a great recent effort have been invested to composite anthraquinone with carbon materials to improve the conductivity. Here we report on a noncovalent way to modify three-dimensional graphene with anthraquinone moieties through on-surface synthesis of two-dimensional covalent organic frameworks. We incorporate 2,6-diamino-anthraquinone moieties into COF through Schiff-base reaction with benzene-1,3,5-tricarbaldehyde. The synthesized COF -graphene composite exhibits large specific capacitance of 31.7 mF/cm(2). Long-term galvanostatic charge/discharge cycling experiments revealed a decrease of capacitance, which was attributed to the loss of COF materials and electrostatic repulsion accumulated during charge-discharge circles which result in the poor electrical conductivity between 2D COF layers." @default.
- W972484264 created "2016-06-24" @default.
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- W972484264 date "2015-08-05" @default.
- W972484264 modified "2023-10-17" @default.
- W972484264 title "3D Graphene Functionalized by Covalent Organic Framework Thin Film as Capacitive Electrode in Alkaline Media" @default.
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- W972484264 doi "https://doi.org/10.1021/acsami.5b04185" @default.
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