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- W976104660 abstract "Publisher Summary This chapter provides an overview of acetylglutamic acid (AGA). N -acetyl-L-glutamic acid is a metabolite in the biosynthesis of ornithine in a number of microorganisms, and it appears to be the “natural” catalyst required for the synthesis of citrulline with ureotelic vertebrate livers. Enzymatic synthesis of AGA from acetyl coenzyme A and L -glutamic acid is catalyzed by Escherichia coli extracts. A good procedure for the chemical synthesis of AGA from acetic anhydride and L -glutamic acid has been reported. The melting point of AGA is 191° to 193°. It is soluble in water and ethanol, but insoluble in benzene, chloroform, acetone, or 12-dimethoxyethane. AGA has been isolated from beef liver and yeast. The isolation was carried out by separation of AGA from the other anions present in hot-water extracts of liver and yeast on a column of Dowex 2 resin by a modification of the procedure for carbamyl- L -glutamic acid. The isolation on the Dowex 2 resin was repeated several times. Cations were then removed by treatment with Dowex 50, and the AGA was finally crystallized from water and then n-butanol, or subjected to paper chromatography followed by crystallization from the concentrated water eluates. The procedure in this chapter is a purely chemical method for the isolation of isotopic AGA from incubation mixtures." @default.
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- W976104660 date "1963-01-01" @default.
- W976104660 modified "2023-09-24" @default.
- W976104660 title "[81] Acetylglutamic acid" @default.
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- W976104660 doi "https://doi.org/10.1016/0076-6879(63)06221-2" @default.
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