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- W97748710 abstract "The modifications of the transport constant of the catalyzed isotopic exchange reaction between hydrogen and water vapor, occurring when the relative concentration of reactants is altered, were studied by adding nitrogen, a gas that does not participate in the reaction, to the mixture. Data on the mechanism of the reaction were obtained by comparing the experimental values with the theoretical values of the transport constant. In order to deduce the theoretical values, the kinetic equations of the reaction were solved by assuming two possible cases for the reaction mechanism: a homogeneous reaction occurring in a single step and an oxidation-reduction type reaction occurring in two steps with the explicit participation of the catalyst. The results obtained have shown that neither of the two hypotheses is entirely satisfactory. With the second hypothesis, however, a more correct quantitative description of the phenomena was obtained. (tr-auth)" @default.
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- W97748710 date "1963-01-01" @default.
- W97748710 modified "2023-09-24" @default.
- W97748710 title "EFFECT OF NITROGEN ON THE ISOTOPIC EXCHANGE REACTION BETWEEN HYDROGEN AND WATER VAPOR" @default.
- W97748710 hasPublicationYear "1963" @default.
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