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- W977599468 abstract "Three new lanthanide phenoxyacetate complexes with 1,10-phenanthroline,[Nd(POA)3(phen)]2·2C2H5OH(1),[Eu(POA)3-(phen)]2·2C2H5OH(2) and [Sm(POA)2(DMSO)(phen)]2-(ClO4)2 (3)(POA=phenoxyacetate,phen=1,10-phenanthroline,DMSO=dimethyl sulfoxide),were synthesized and characterized by elemental analyses,IR,UV-vis and FAB-MS spectra.Their structures were determined by single crystal X-ray diffraction analysis.In complexes 1 and 2,the carboxlyate groups are bonded to Ln^3+ ion in three modes:the chelating bidentate,the bridging bidentate and the bridging tridentate.In complex3,the carboxylate groups are bonded to Sm^3+ ion only involved in one mode:the bridging bidentate.The luminescence behavior of complex 2 was also studied by means of emission spectra." @default.
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- W977599468 date "2003-01-01" @default.
- W977599468 modified "2023-09-23" @default.
- W977599468 title "Synthesis,Charactarization and Crystal Structures of Lanthanide Phenoxyacetate Complexes with1,10—Phenanthroline" @default.
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