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- W977774802 abstract "木文报道了钴(Ⅱ,Ⅲ)与meso-四(4-苯基磺基)卟啉(TPPS)络合物的形成条件和电还原行为.结果表明在醋酸缓冲溶液(pH3.5)中,Co 2+ -TPPS还原同时产生催化氢波.在氨性缓冲溶液(pH9.0)中,Co 2+ -TPPS产生络合吸附波,讨论了其伏安行为,认为络合物中Co 2+ 和TPPS是一步同时还原.溶解氧可以把Co 2+ -TPPS氧化为Co 3+ -TPPS,对比Mn 3+ -TPPS讨论了络合物的形成和溶解氧的作用,认为氧对卟啉络合物中心离子价态变化和电子转移起着重要作用." @default.
- W977774802 created "2016-06-24" @default.
- W977774802 creator A5004162373 @default.
- W977774802 creator A5069143326 @default.
- W977774802 date "1993-09-24" @default.
- W977774802 modified "2023-09-24" @default.
- W977774802 title "钴(II,III)与meso-四(4-苯基磺基)卟啉(TPPS)络合物的伏安行为研究" @default.
- W977774802 hasPublicationYear "1993" @default.
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