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- W97844729 abstract "Amino boronate based bifiinctional molecules have the potential to be powerful catalysts. Herein, a number of approaches to the bifimctional benzimidazole catalyst 1 are described, and the synthesis of a number of analogues are explored. Investigations into the potential of 2-(2-boronobenzene)- 2N-n-butylbenzimidazole sodium hydroxide salt 1 as a catalyst for a number of synthetic transformations, including an aza-version of the Baeyer-Villiger reaction (Equation 1), are described The 2-(2-boronobenzene)-N-n-butylbenzimidazole sodium hydroxide salt 1 is shown to be active in the aldol condensation reaction (Equation 2)， Knoevenagel reaction, and evidence for the promotion of the Michael reaction by 1 is presented. The mechanism by which the aldol condensation reaction is promoted by 1 is explored through kinetic studies." @default.
- W97844729 created "2016-06-24" @default.
- W97844729 creator A5027771599 @default.
- W97844729 date "2005-01-01" @default.
- W97844729 modified "2023-09-23" @default.
- W97844729 title "Exploration of new catalytic methodologies for heterocyclic synthesis and C-C Bond Formation." @default.
- W97844729 hasPublicationYear "2005" @default.
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