FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W978680748> ?p ?o ?g. }

• W978680748 endingPage "63" @default.
• W978680748 startingPage "55" @default.
• W978680748 abstract "Abstract The reaction of trans -[PtCl 2 (NCR) 2 ] (R 1  = CH 2 CO 2 Me ( 1a ), R 2  = CH 2 Cl ( 1b )) with pyrroline N -oxide − O + N CHCH 2 CH 2 C Me 2 ( 4 ), at room temperature for 15 min, furnishes via [3+2] cycloaddition the fused bicyclic Δ 4 -1,2,4-oxadiazoline Pt(II) complexes trans- [PtCl 2 { N C(R)O N C(H)CH 2 CH 2 C Me 2 } 2 ] (R 1  = CH 2 CO 2 Me ( 5a ), R 2  = CH 2 Cl ( 5b )). Compounds 5a and 5b were refluxed in CH 2 Cl 2 for 1 week to afford the derived ketoimine Pt(II) complexes trans- [PtCl 2 {N(C( O)(R)) C CH 2 CH 2 C(Me 2 ) N H} 2 ] (R 1  = CH 2 CO 2 Me ( 6a ), R 2  = CH 2 Cl ( 6b )), respectively, as a result of the N–O bond cleavage of the oxadiazoline ring in 5 . The complexes were characterized by IR, 1 H and 13 C NMR spectroscopies, ESI + -MS and elemental analyses. DFT calculations show that the Pt(II)-catalysed [3+2] cycloaddition reaction ( 4  +  10 → 11 ) is spontaneous and exergonic. In addition, the reaction is completely regioselective yielding a unique oxadiazoline. Moreover, the molecular structure, spectroscopic and electronic properties of complex 5b were predicted, and the optimized geometry showed a slightly distorted square planar arrangement around the Pt(II) centre." @default.
• W978680748 created "2016-06-24" @default.
• W978680748 creator A5029149793 @default.
• W978680748 creator A5038768694 @default.
• W978680748 creator A5049851891 @default.
• W978680748 creator A5054833888 @default.
• W978680748 creator A5087539611 @default.
• W978680748 date "2015-09-01" @default.
• W978680748 modified "2023-10-10" @default.
• W978680748 title "Synthesis, molecular structure and stability of fused bicyclic Δ4-1,2,4-oxadiazoline Pt(II) complexes" @default.
• W978680748 cites W1499044455 @default.
• W978680748 cites W1963737263 @default.
• W978680748 cites W1973096409 @default.
• W978680748 cites W1974671229 @default.
• W978680748 cites W1979778619 @default.
• W978680748 cites W1983957163 @default.
• W978680748 cites W1987702006 @default.
• W978680748 cites W1990865382 @default.
• W978680748 cites W1991637860 @default.
• W978680748 cites W1993383767 @default.
• W978680748 cites W2004283817 @default.
• W978680748 cites W2008708918 @default.
• W978680748 cites W2010798461 @default.
• W978680748 cites W2023271753 @default.
• W978680748 cites W2024414717 @default.
• W978680748 cites W2024913248 @default.
• W978680748 cites W2029867653 @default.
• W978680748 cites W2030877330 @default.
• W978680748 cites W2032373722 @default.
• W978680748 cites W2038083805 @default.
• W978680748 cites W2038767330 @default.
• W978680748 cites W2040676878 @default.
• W978680748 cites W2041278434 @default.
• W978680748 cites W2042792117 @default.
• W978680748 cites W2043125829 @default.
• W978680748 cites W2049193616 @default.
• W978680748 cites W2049755052 @default.
• W978680748 cites W2049971681 @default.
• W978680748 cites W2055692222 @default.
• W978680748 cites W2057351188 @default.
• W978680748 cites W2060153452 @default.
• W978680748 cites W2061398342 @default.
• W978680748 cites W2061944411 @default.
• W978680748 cites W2066484101 @default.
• W978680748 cites W2077231682 @default.
• W978680748 cites W2083396753 @default.
• W978680748 cites W2084619794 @default.
• W978680748 cites W2085837863 @default.
• W978680748 cites W2086958494 @default.
• W978680748 cites W2090327784 @default.
• W978680748 cites W2090821020 @default.
• W978680748 cites W2091396606 @default.
• W978680748 cites W2091557006 @default.
• W978680748 cites W2092950608 @default.
• W978680748 cites W2093574720 @default.
• W978680748 cites W2103262721 @default.
• W978680748 cites W2106021720 @default.
• W978680748 cites W2115789720 @default.
• W978680748 cites W2123276395 @default.
• W978680748 cites W2133524519 @default.
• W978680748 cites W2143981217 @default.
• W978680748 cites W2230728100 @default.
• W978680748 cites W2320310037 @default.
• W978680748 cites W2952690968 @default.
• W978680748 cites W4231649355 @default.
• W978680748 doi "https://doi.org/10.1016/j.poly.2015.05.039" @default.
• W978680748 hasPublicationYear "2015" @default.
• W978680748 type Work @default.
• W978680748 sameAs 978680748 @default.
• W978680748 citedByCount "7" @default.
• W978680748 countsByYear W9786807482017 @default.
• W978680748 countsByYear W9786807482018 @default.
• W978680748 countsByYear W9786807482019 @default.
• W978680748 countsByYear W9786807482020 @default.
• W978680748 countsByYear W9786807482022 @default.
• W978680748 crossrefType "journal-article" @default.
• W978680748 hasAuthorship W978680748A5029149793 @default.
• W978680748 hasAuthorship W978680748A5038768694 @default.
• W978680748 hasAuthorship W978680748A5049851891 @default.
• W978680748 hasAuthorship W978680748A5054833888 @default.
• W978680748 hasAuthorship W978680748A5087539611 @default.
• W978680748 hasConcept C147597530 @default.
• W978680748 hasConcept C185592680 @default.
• W978680748 hasConcept C24961977 @default.
• W978680748 hasConcept C71240020 @default.
• W978680748 hasConcept C8010536 @default.
• W978680748 hasConceptScore W978680748C147597530 @default.
• W978680748 hasConceptScore W978680748C185592680 @default.
• W978680748 hasConceptScore W978680748C24961977 @default.
• W978680748 hasConceptScore W978680748C71240020 @default.
• W978680748 hasConceptScore W978680748C8010536 @default.
• W978680748 hasFunder F4320322930 @default.
• W978680748 hasLocation W9786807481 @default.
• W978680748 hasOpenAccess W978680748 @default.
• W978680748 hasPrimaryLocation W9786807481 @default.
• W978680748 hasRelatedWork W1531601525 @default.
• W978680748 hasRelatedWork W1979111880 @default.
• W978680748 hasRelatedWork W2093861474 @default.

• next