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- W98256054 abstract "In the present study, a comprehensive mathematical model is developed to predict the evolution of particle size distribution (PSD) in a gas-phase olefin polymerization fluidized bed reactor (FBR). To calculate the particle growth and the spatial monomer and temperature profiles in a particle, the random pore polymeric flow model (RPPFM) is employed. The RPPFM is solved together with a dynamic population balance model, accounting for both particle growth and agglomeration, to predict the PSD in the bed. To evaluate the extent of particle agglomeration in the bed, a new agglomeration kernel is developed in terms of the individual particle surface temperatures, the polymer softening temperature and a size dependent function, describing the mechanism of dual particle collisions. The effects of bulk polymerization temperature and propylene to ethylene molar ratio on the extent of particle agglomeration in an FBR are thoroughly analyzed." @default.
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- W98256054 date "2004-01-01" @default.
- W98256054 modified "2023-09-25" @default.
- W98256054 title "Dynamic evolution of the particle size distribution in gas-phase olefin polymerization fluidized bed reactors" @default.
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- W98256054 doi "https://doi.org/10.1016/s1570-7946(04)80239-6" @default.
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