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- W983334078 abstract "The thermal stability of Mn12-Ac[Mn12(CH3COO)16(H2O)4O12]52CH3COOH54H2O magnetic molecular crystals was investigated by TG-DTA from room temperature to 270℃. According to the results of XRD and TG,we found that Mn12-Ac lost the crystal water and the acetic acid molecules of solvation which were located between the adjacent molecules in the temperature range from 25℃ to 1 10℃. At the same time, 4H2O which were linked with 4 Mn3+ were lost. The crystalline structure of Mn12-Ac single crystal was destroyed during this course. However, the core structure in the molecule was well preserved. From 180℃ to 230℃, a further transformatio n took place, Mn12-Ac lost all the CH3COO- ions and turned intoγ-Mn2O3, with a little amount of Mn3O4." @default.
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- W983334078 date "2004-01-01" @default.
- W983334078 modified "2023-10-16" @default.
- W983334078 title "Thermal analysis and structure transformation of Mn12-Ac magnetic molecular crystals" @default.
- W983334078 doi "https://doi.org/10.7498/aps.53.4015" @default.
- W983334078 hasPublicationYear "2004" @default.
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