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- W983435725 abstract "The results of a two-stage conversion of brown coal (gross-formula CH0.96N0.01S0.002O0.31) in supercritical water (SCW) under isobaric conditions (30 MPa) in the vertical tubular reactor of an original configuration are presented. The first stage provides for a continuous supply of coal–water slurry (CWS) into the reactor and discharging of the products with SCW into the demountable samplers. The CWS composition was as follows (weight portions): coal—100, water—125, and starch—2.25. It was found out that when increasing the temperature of coal particles up to 600 °C during their falling down along the reactor axis, the yields of volatile and liquid products were 25.4 and 27.5%, respectively, relative to the weight of organic matter supplied into the reactor. At the second stage of conversion, the SCW/O2 fluid was pumped through a layer of coal particles accumulated at the reactor bottom during the first stage. It was shown that as a result of heat emission during partial oxidation of coal residue, the autothermal conditions for conversion were realized. The yields of volatile combustible and liquid products at conversion in the SCW/O2 fluid were 25.1 and 3.4 wt.%, respectively. The increment of hydrogen in the conversion products caused by water decomposition was equal to 20% relative to the weight of hydrogen in initial coal." @default.
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- W983435725 date "2016-01-01" @default.
- W983435725 modified "2023-09-30" @default.
- W983435725 title "Conversion of brown coal continuously supplied into the reactor as coal–water slurry in a supercritical water and water–oxygen mixture" @default.
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- W983435725 doi "https://doi.org/10.1016/j.supflu.2015.07.035" @default.
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