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- W984944698 abstract "This chapter discusses the sources of compilations of rate constants for oxygen radicals (hydroxyl radical, perhydroxyl radical, singlet oxygen, alkoxyl, aroxyl, and alkylperoxyl radicals) in solution. Rate constants for about 1,500 reactions involving the hydroxyl radical and its conjugate base in aqueous solution have been collected in a critical compilation. The data are available in the RATES database. A comprehensive compilation of reactions of the lowest electronically excited singlet state of molecular oxygen with 690 organic and inorganic species in solution, complete through 1978, was published. It is estimated that the number of reactions for which the rate constants are available has at least doubled in the decade since this compilation was completed. Updating and reevaluation of the data are in progress. A volume in the Landolt–Boernstein series 5 contains absolute rate constants for over 100 reactions involving alkoxyl radicals, rate constants for over 200 reactions involving aroxyl radicals, and rate constants involving over 1,000 reactions of alkylperoxyl radicals. Data obtained in both aqueous and nonaqueous solutions are reported. The online database RATES contains aqueous solution rate constants for the reactions of inorganic radicals, including oxy radicals. The published versions of the data have appeared and periodic updates of the online version are carried out. Direct dial access to the database is available. The database is integrated with a bibliographic database (RCDCbib) and a registry file (RCDCreg), which contains substance information for the chemical species." @default.
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- W984944698 date "1990-01-01" @default.
- W984944698 modified "2023-09-26" @default.
- W984944698 title "[5] Sources of compilations of rate constants for oxygen radicals in solution" @default.
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- W984944698 doi "https://doi.org/10.1016/0076-6879(90)86097-f" @default.
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