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- W986259093 abstract "Publisher Summary This chapter describes the movement of protons in inorganic materials. Inorganic materials may be solid, liquid, or gaseous. It focuses on the protonic movements within solids or at a solid–liquid interface. The proton is unique in the character of its bonding, and hence in the variety of movements available to it. In proton bonding, it is necessary to distinguish the hydrogen bonding in hydrides from that encountered in ionic compounds. In a metal hydride, a hydrogen atom has several equivalent nearest-neighbor metal atoms. The hydrogen atoms move through the host metal in a diffusive motion, the protonic core and its associated electronic cloud moving together. Such a motion is classified as proton–electron diffusion. Five basic proton movements described in the chapter are proton–electron diffusion, proton displacement, proton-electron displacement, piggyback rotation, and piggyback diffusion. Two types of motion are known, namely––tunneling and diffusion. Tunneling occurs where a donor state and an acceptor state on either side of the barrier have overlapping wave functions. Diffusion describes the jumping of a particle among equivalent potential wells across a potential-energy barrier." @default.
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- W986259093 date "1986-01-01" @default.
- W986259093 modified "2023-09-27" @default.
- W986259093 title "[19] Proton movements in inorganic materials" @default.
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- W986259093 doi "https://doi.org/10.1016/0076-6879(86)27022-6" @default.
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