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- W986694092 endingPage "224" @default.
- W986694092 startingPage "161" @default.
- W986694092 abstract "This chapter states that the reaction of carbohydrates in alkaline or acidic aqueous solutions results in a myriad of products, many of which have been recognized for well over a century. With the exception of anhydro sugars and oligosaccharides, found as concentration-dependent, equilibrium constituents in acidic solutions, all of the products result from reactions of intermediates. The dehydration reactions initiated by eliminating a hydroxyl group from an enediol are discussed in the chapter. The products of these eliminations are normally transient intermediates, and undergo further reaction. The final products formed are determined by the carbohydrate reacting, the conditions of reaction, and the character of the medium. In the degradation reactions of sugars, major structural differences exist between products and reactants: in acidic solution, pyranoses produce furan compounds; in basic solution, acyclic saccharinic acids are formed. The acyclic enediols produced from acyclic sugars, which are the intermediates in the isomerization, are also the reactive components that initiate the degradation reactions and the dehydration products may be regarded as products of a side reaction of the transformation." @default.
- W986694092 created "2016-06-24" @default.
- W986694092 creator A5010151617 @default.
- W986694092 creator A5014575056 @default.
- W986694092 date "1973-01-01" @default.
- W986694092 modified "2023-10-14" @default.
- W986694092 title "Dehydration Reactions of Carbohydrates" @default.
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