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- W98686376 abstract "The coordinating properties of the dithiaphospholane ligands RPSCH2CH2S and RPS(o-C6H4)S (R = CH3, CF3) have been studied by synthesis and spectroscopic investigations (IR, NMR, MS) of their chromium complexes Cr(CO)5L (1-4) and cis-Cr(CO)4L2 (5-8). Complexes 1-4 are obtained by indirect photochemical substitution via Cr(CO)5THF, compounds 5-8 by replacement of norbornadiene (NBD) in Cr(CO)4NBD. Spectroscopic data [v (CO), Δδ support the σ-donor/π-acceptor model of the CrP bond and the influence of mesomeric in addition to inductive and steric effects. Die Koordinationseigenschaften der Dithiaphospholan-Liganden RPSCH2CH2S und RPS(o-C6H4)S (R = CH3, CF3) werden durch Synthese und spektroskopische Untersuchungen (IR, NMR, MS) der Chromkomplexe Cr(CO)5L (1-4) und cis-Cr(CO)4L2 (5-8) überprüft. Die Komplexe 1-4 werden durch indirekte photochemische Substitution über die Zwischenstufe Cr(CO)5THF, die Verbindungen 5-8 durch Ersatz von Norbornadien (NBD) aus Cr(CO)4NBD erhalten. Die spektroskopischen Daten [v (CO), Δδ] stützen das σ-Donor/π-Akzeptor-Modell der CrP-Bindung und den Einfluss mesomerer neben induktiven und sterischen Effekten." @default.
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- W98686376 date "1985-07-01" @default.
- W98686376 modified "2023-09-27" @default.
- W98686376 title "Perfluormethyl-element-liganden" @default.
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- W98686376 doi "https://doi.org/10.1016/0022-328x(85)87411-8" @default.
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