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- W98792372 abstract "Recent progress in the development and application of chromatographic and ZLC methods to the measurement of intracrystalline diffusion in zeolites is reviewed. For hydrocarbons in silicalite the results show the expected pattern of variation of diffusivity with the size and shape of the sorbate molecule but for the unsaturated hydrocarbons, an unexpected variation of diffusivity with loading, at very low concentrations, is observed. The variation of diffusivity with chain length for the n-alkanes in offretite-erionite has also been investigated in detail and there appears to be no evidence to support the widely quoted “window effect” for this system. Comparisons between macroscopic and microscopic diffusivity measurements are presented and although there is good agreement for many systems, some troubling discrepancies remain." @default.
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- W98792372 date "2006-02-24" @default.
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- W98792372 title "Recent Progress in the Study of Intracrystalline Diffusion in Zeolites by Chromatographic and ZLC Techniques" @default.
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- W98792372 doi "https://doi.org/10.1007/0-306-47066-7_13" @default.
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