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- W98900193 abstract "Abstract Besides Li + and Mg 2+ , the electrochemical behavior of Na + and K + in LiFePO 4 / FePO 4 structures was studied since they naturally coexist with Li + and Mg 2+ in brine. The cyclic voltammogram (CV) results indicated that Na + exhibits some reversibility in LiFePO 4 /FePO 4 structures. Its reduction peak appears at −0.511 V, more negative than that of Li + (−0.197 V), meaning that a relatively positive potential is beneficial for decreasing Na + insertion. The reduction peak of K + could not be found clearly, indicating that K + is difficult to insert into the FePO 4 structure. Furthermore, technical experiments using real brine with a super high Mg/Li ratio (493) at a cell voltage of 0.7V showed that the final extracted capacity of Li + , Mg 2+ and Na + that can be attained in 1 g LiFePO 4 is 24.1 mg, 7.32 mg and 4.61 mg, respectively. The Mg/Li ratio can be reduced to 0.30 from 493, and the Na/Li ratio to 0.19 from 16.7, which proves that, even in super high Mg/Li ratio brine, if a cell voltage is appropriately controlled, it is possible to separate Li + and other impurities effectively." @default.
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- W98900193 date "2013-04-01" @default.
- W98900193 modified "2023-10-14" @default.
- W98900193 title "Electrochemical behavior of Li+, Mg2+, Na+ and K+ in LiFePO4/ FePO4 structures" @default.
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- W98900193 doi "https://doi.org/10.1016/s1003-6326(13)62578-9" @default.
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