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- W99006061 abstract "Highly conjugated conducting polymers are known to be excellent materials for electronic devices like electrolytic capacitors, actuators, sensors, artificial muscles, and lightemitting diodes (LEDs). In particular, low band gap conducting polymers draw much attention because they potentially provide materials with high conductivities as well as desirable optical properties. The first low band gap conducting polymer, poly (isothianaphthene), which was reported by Wuld et al. and its band gap was about 1 eV. This is caused by the intrinsic structure of the polymer backbone which trends to stabilize the electronic quinoid state. Several low band gap conducting polymers derived from thieno[3,4-b]pyrazine, isothianaphthene and thieno[3,4-b]thiophene have been reported. From Bredas and his co-workers, the band gap is more or less proportional to the bond length alternation along the polymer backbone. In particular, polythiophene with increased quinoid form reduces the band gap. 4b, 5 Recently, we have reported a series of solution processible low band gap conducting polymers such as poly(1-dodecyl-2,5-pyrrolylenevinylene) (Eg = 1.67 eV) and poly(3,4-ethylenedioxypyrrole) (Eg = 1.57 eV). Herein, we now communicate the new successful synthesis, characterization, and properties of poly(2-nonylthieno[3,4d]thiazole) (1) as a new solution processible low band gap conducting polymer and a new preparative route to 2-alkylthieno[3,4-d]thiazole that can be applicable to synthesize the new conducting polymer as shown in Scheme 1." @default.
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- W99006061 date "2007-12-20" @default.
- W99006061 modified "2023-09-29" @default.
- W99006061 title "New Low Band Gap Conjugated Conducting Poly(2-nonylthieno[3,4-d]thiazole): Synthesis, Characterization, and Properties" @default.
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- W99006061 doi "https://doi.org/10.5012/bkcs.2007.28.12.2511" @default.
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