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• W99205887 endingPage "203" @default.
• W99205887 startingPage "132" @default.
• W99205887 abstract "This chapter discusses principles of small molecule–DNA recognition. The task of DNA sequence recognition has as its prerequisite knowledge of the frequency of occurrence of a DNA sequence within a defined length of DNA. This can be directly obtained from a DNA databank if the entire target sequence is known, which is now the case for the human genome, and for genomes in many other species, eukaryotic and prokaryotic. In order for direct readout to occur, an incoming molecule has to access the base pairs via a DNA groove. The orientation of this incoming group is important since hydrogen bonding to and from bases, and hence direct readout, are predominantly directional interactions. The edges of the bases in Watson–Crick duplex DNA have hydrogen-bonding potential that is only partially satisfied by base pairing itself and therefore is available for recognition by ligand with hydrogen-bonding complementarity. This pattern of hydrogen-bond donation and acceptance has built-in sequence dependency." @default.
• W99205887 created "2016-06-24" @default.
• W99205887 creator A5003587331 @default.
• W99205887 date "2008-01-01" @default.
• W99205887 modified "2023-10-18" @default.
• W99205887 title "Principles of Small Molecule-DNA Recognition" @default.
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