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- W993268270 abstract "This chapter discusses the thermodynamic calculations for the reactions which a number of active metals containing carbon undergo, when heated in a high vacuum system. The most fruitful approach to the understanding of many surface reactions is to study the kinetics of the reaction together with spot checks on the several structural factors. Because, the measurements may be carried out over a period of several hours to several days, it is essential to design the balance and its supports so that the effect of any thermal change will be minimized. The important factors involved are: (1) the relative length of the two halves of the balance beam, (2) the torsional resistance of the supporting wire, (3) the relative position of the beam to the supporting frame, and (4) torsional resistance of the end-supporting wires. For purposes of classification, the several materials of the experimental unit is divided into three groups. These are the materials used in the individual parts of the vacuum system, the materials used for connecting its parts, and the specimen and its support." @default.
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- W993268270 date "1953-01-01" @default.
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- W993268270 title "Surface Studies with the Vacuum Microbalance: High-Temperature Reactions" @default.
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- W993268270 doi "https://doi.org/10.1016/s0360-0564(08)60641-0" @default.
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