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- W994035719 abstract "The reaction of triphenylphosphine with AgNO3 yielded an unusual nitrate anion bridging one-dimensional infinite chain [Ag(PPh3)NO3]∞ in which the silver(Ⅰ) atom is three-coordinated by one P atom of triphenylphosphine and two O atoms of two bridging nitrate anions to form a scalene triangle. The complex [Ag(PPh3)NO3]∞ crystallizes in the monoclinic system, space group P21/c with a=10.281(2), b=18.596(5), c=9.180(2)A°, β=90.60(1)°, V=1755.1(7)A°3, Z=4, Mr=432.15, Dc=1.635 g/cm^3, F(000)=864 and μ=1.254mm^-1. The final R=0.0606 and wR=0.1400 for 2188 observed reflections with Ⅰ>2σ(Ⅰ) out of 3057 unique ones (Rint=0.0539). IR and elemental analysis of the complex are characterized." @default.
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- W994035719 date "2004-01-01" @default.
- W994035719 modified "2023-09-24" @default.
- W994035719 title "Synthesis and Structural Characterization of a New One-dimensional Infinite Chain of Silver（I） Complex with Triphenylphosphine" @default.
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