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- W994732940 abstract "A trinuclear linear Mo-Fe-Mo dialkyldithiocarbamate complex [Et4N] { [ Me2dtcMoO (μ-S)2 ]2Fe} has been obtained and structurally characterized, which contains two Me2dtcMoO-(μ-S)2 units coordinated to a central tetrahedral Fe atom. A comparison of the structural parameters indicates the metal oxidation states of 2Mo(v) + Fe(III). The 1H NMR shows chemical shifts of Me2dtc ligands at 5 10.14 and 8 9.40 with the intensity ratio of 1:1. The cyclic voltammogram displays a reversible couple at - 1.41 V/ - 1.36 V responsible for 1-/2-anions of the complex and an irreversible oxidation at 0.5 V, which seems to show the apparent lack of stability for its neutral species (Me2dtcMoOS2)2Fe." @default.
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- W994732940 date "2000-01-01" @default.
- W994732940 modified "2023-09-23" @default.
- W994732940 title "A trinuclear Mo-Fe-Mo cluster compound [Et 4 N] { [Me 2 dtcMo-O（μ-S） 2 ] 2 Fe} containing dialkyldithiocarbamate ligand" @default.
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