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- W996013568 abstract "Publisher Summary This chapter focuses on the solubility of hydroxyaluminosilicates (HAS (s) ) and the biological availability of aluminum. HAS (s) are formed in solutions in which the precipitation of Al(OH) 3(s) is approached from either acidic or basic conditions or where Si(OH) 4(aq) is mixed with preformed Al(OH) 3(s) . The initial step in the formation of HAS (s) is the “competitive” condensation of Si(OH) 4(aq) across adjacent hydroxyl groups on a framework of Al(OH) 3(s) . HAS A(s) are composed of aluminum and silicon in the ratio of 2:1 and are the predominant form of HAS (s) in solutions in which the initial [Si(OH) 4(aq) ] is less than or equal to [Al T ]. HASB (s) are composed of aluminum and silicon in the ratio of 1:1 and are the predominant form of HAS (s) in solutions in which the initial [Si(OH) 4(aq) ] is significantly in excess (more than twice) of [Al T ]. The formation of HASA (s) is a prerequisite to the formation of HASB (s) , irrespective of the initial solution ratio of Si(OH) 4(aq) and Al T . Thus, HASB (s) are formed via the further condensation of Si(OH) 4(aq) across adjacent hydroxyl groups on a framework of HASA (s) . HAS (s) are effective in limiting the biological availability of aluminum because of their kinetic inertia. Under certain conditions, HAS (s) have been shown to aggregate much more slowly toward their critical size than Al(OH) 3(s) , and it is under such conditions that HAS (s) are less stable toward dissolution than Al(OH) 3(s) . Consequently, HAS (s) are the potent sources of biologically available aluminum." @default.
- W996013568 created "2016-06-24" @default.
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- W996013568 date "2007-01-01" @default.
- W996013568 modified "2023-09-26" @default.
- W996013568 title "The Solubility of Hydroxyaluminosilicates and the Biological Availability of Aluminium" @default.
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- W996013568 doi "https://doi.org/10.1016/b978-044452707-3/50019-7" @default.
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