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- W996353428 abstract "The electrochemical properties and structure of MINi5-xSnx(x = 0-0.5) hydrogen storage alloys were investigated by pressure-composition isotherms, electrochemical measurements, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and atomic parameters. With a small amount of tin substitution, the cycle life increases by 52% (0.5C) and 42% (1.0C), but maximum discharge capacity decreases only by 3.0% and 3.5%, respectively. The cycle life is obviously improved by the low vo!ume expansion and the formed SnO2 surface layers upon electrochemical cycling. The substitution of Ni by Sn leads to an increase of the unit cell volume and charge-discharge cycle life and decrease of the plateau pressure, hysteresis and the hydrogen storage capacity. The standard enthalpy of hydride formation decreases with increasing tin substitution. The main factor that influences the standard enthalpy of the hydriding reaction is the number of the outer orbit electrons and not the atomic size factor." @default.
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- W996353428 date "2002-01-01" @default.
- W996353428 modified "2023-09-24" @default.
- W996353428 title "Electrochemical properties and structure of MINi5-xSnx system" @default.
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