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- W996911690 abstract "Interpretation of Crystal Field Parameters with Additive Models This chapter discusses an effective method of the interpretation of experimental data in f- electron ionic systems, paying a special attention to simplified crystal field (CF) models based on the partitioning of the CF potential. These simplified models are of invaluable help in the burdensome ambiguity problem connected intimately with the standard parameteric analysis. Several further areas of application are indicated that are equally promising. The theoretical grounds of the models, their shortcomings and advantages are discussed, and the general frames of the interpretation routine are sketched in the chapter. The list of possible applications of the simplified models is certainly not complete, but it conveys an idea of their usefulness. Efficiency of the twin superposition model may be similar in some cases, but in light of the ab initio calculations, the angular overlap model provides the parameters that seem to be more natural and more appropriate for both comparison and classification, as well as for anticipation of their values." @default.
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- W996911690 date "2000-01-01" @default.
- W996911690 modified "2023-09-26" @default.
- W996911690 title "Analysis of the experimental data. Interpretation of crystal field parameters with additive models" @default.
- W996911690 doi "https://doi.org/10.1016/b978-008043608-1/50017-4" @default.
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