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- W996980796 abstract "The interaction of hydrogen with Ni powder and supported nickel catalysts was studied by temperature-programmed desorption (TPD) method. The measurements of hydrogen desorption were started at about 100 K, which resulted in formation of extended spectra of hydrogen chemisorbed on nickel. Preliminary examinations of the spectra indicate that at low temperature considerable quantity of hydrogen is located in subsurface region of nickel. Quantitative analysis of the spectra recorded for Ni powder showed that at low temperature the stoichiometry of hydrogen chemisorption on nickel, i.e. H/Ni, ratio, is close to 1.8. The studies of hydrogen adsorption on supported nickel catalysts indicate that commonly applied measurements of hydrogen adsorption at room temperature are justified for characterization of Ni/Al 2 O 3 , but appear inappropriate for Ni/SiO 2 ." @default.
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- W996980796 title "Adsorption of hydrogen on unsupported and supported nickel" @default.
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