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- W998707285 abstract "由于含硫铜(Ⅰ)化合物表现出生物相关性[1]、能发出不同颜色的荧光[2～4],因而引起化学工作者的广泛关注[5].尽管标题化合物含硫六核铜簇合物合成和晶体结构已见报道[6],但本文采用[Cu(PPh3)2(MeCN)2]ClO4与2-巯基-N-氧化吡啶分别代替了文献[6]采用的[Cu(MeCN)2]BF6和2-巯基吡啶,水热法合成了六(2-巯基吡啶六铜(Ⅰ)簇合物,经元素分析、IR、单晶X射线衍射结构分析确定其组成和结构与文献报道[6]一致.采用美国PE公司的Pyris Diamond热重分析仪和LS-50B型荧光分析仪分别测定它在N2气气氛中的热稳定性和荧光发射性质,证明该化合物在空气中稳定、热稳定性较高、室温下λ=468nm波长光激发可发出很强的λ=744nm低能荧光,在半导体荧光材料和发光二极管(LED)等方面具有潜在的应用前景[7]." @default.
- W998707285 created "2016-06-24" @default.
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- W998707285 date "2005-11-10" @default.
- W998707285 modified "2023-09-24" @default.
- W998707285 title "新法合成Cu6(C5H4NS)6簇合物及其性质" @default.
- W998707285 hasPublicationYear "2005" @default.
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